o Three competitive transition states in the benzoin condensation compared to the clear rate-determining step in the Cannizzaro reaction. Intramolecular catalysis. On the origin of hydrogen in the formaldehyde reaction in alkaline solution. Sebastian Koller, Max Blazejak, Lukas Hintermann. Please note: If you switch to a different device, you may be asked to login again with only your ACS ID. 2 Yuki Yamasaki, Heiji Enomoto, Nakamichi Yamasaki, Masaru Nakahara. Microwave-accelerated crossed Cannizzaro reaction using barium hydroxide under solvent-free conditions. Ultra-thin TiO Highly efficient hydrogen production from alkaline aldehyde solutions facilitated by palladium nanotubes. Martin Elsener, Rob Jeremiah G. Nuguid, Oliver Kröcher, Davide Ferri. Palladium nanoparticles supported on organosilane-functionalized carbon nanotube for solvent-free aerobic oxidation of benzyl alcohol. This is followed by deprotonation to give a dianion. Reactions of [RuClH(CO)(PPh3)3] with 2-methyl-2-propen-1-ol. NMR Study of Hydrothermal Reactions of Dichloromethane with and without Alkali. The reaction requires a strong base as the catalyst. Yan Li, Xinfa Wei, Lisong Chen, Jianlin Shi, Mingyuan He. Metal Ion Catalysis of Natural Products Transformations. the Altmetric Attention Score and how the score is calculated. Bulletin of the Chemical Society of Japan. Fun interactive learning with in-class quizzes and leaderboards.4. Relationship between Acid-Base Properties and the Activity of ZrO Ya. The enantioselectivity of quinohaemoprotein alcohol dehydrogenases: mechanistic and structural aspects. Oxidant-Free Transformation of Ethylene Glycol toward Glycolic Acid in Water. E.E. Process Development and Scale-Up of PPAR α/γ Dual Agonist Lobeglitazone Sulfate (CKD-501). Decarboxylative Trichloromethylation of Aromatic Aldehydes and Its Applications in Continuous Flow. Kyunghoon Lee, Jin Woo Kim, Woo Youn Kim. -oxides. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Jens Uhlemann, Michel Cabassud, Marie-Véronique Le Lann, Elisabeth Borredon, Gilbert Casamatta. Structure and Base Catalysis of Supercritical Water in the Noncatalytic Benzaldehyde Disproportionation Using Water at High Temperatures and Pressures. Pankaja K. Kadaba, Gordon Parmley, Peter A. Crooks, Bushra Agha. MECHANISM OF CANNIZZARO REACTION * The Cannizzaro reaction is initiated by the nucleophilic attack of a hydroxide ion on the carbonyl carbon of an aldehyde molecule by giving a hydrate anion, which can be further deprotonated to give a dianion in a strongly alkaline medium. -Based Catalysts for the Cannizzaro Reaction of Pyruvaldehyde to Lactic Acid. HCN production from formaldehyde during the selective catalytic reduction of NOx with NH3 over V2O5/WO3-TiO2. High efficient photocatalytic hydrogen evolution from formaldehyde over sensitized. ]biphenyl-2,2′-dicarbaldehyde and 4,4′-or 5,5′- or 6,6′-disubstituted biphenyl-2,2′-dicarbaldehydes. Studies towards the total synthesis of taxoids. Yutaka Ikushima, Kiyotaka Hatakeda, Osamu Sato, Toshirou Yokoyama, Masahiko Arai. In the reaction, two molecules of aldehyde react to yield a carboxylic acid and a primary alcohol. 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