Pt nanoparticle supported on nanocrystalline CeO For reproduction of material from all other RSC journals and books: For reproduction of material from all other RSC journals. is available on our Permission Requests page. Find more information about Crossref citation counts. Reproduced material should be attributed as follows: If the material has been adapted instead of reproduced from the original RSC publication The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Chemoselectivity can be tuned via regulating the reaction medium including alkalinity and the hydrogen source. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China Completing the CAPTCHA proves you are a human and gives you temporary access to the web property. Herein we carried out the first work on the simultaneous transformation of glucose to arabinose and of nitrosobenzene to azoxybenzene by photocatalysis. Your Mendeley pairing has expired. This article is cited by © 2020 Elsevier Inc. All rights reserved. Cloudflare Ray ID: 5f795174dac4f0c5 do not need to formally request permission to reproduce material contained in this Elimination of water in both reactions produces azobenzene and azoxybenzene respectively. The reaction mechanism and the reason for the high selectivity were studied using control experiments. Your IP: 70.32.66.20 songjl@iccas.ac.cn, hanbx@iccas.ac.cn. If you are at an office or shared network, you can ask the network administrator to run a scan across the network looking for misconfigured or infected devices. The azoxybenzene can be further reduced to azobenzene. Information about reproducing material from RSC articles with different licences Davood Azarifar, Seyed-Mola Khatami, Zohreh Najminejad. Song, T. Wu, H. Liu, C. Xie, G. Yang and B. Han, Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Colloid and Interface and Thermodynamics, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China, Instructions for using Copyright Clearance Center page. * DOI For reproduction of material from all other RSC journals and books: For reproduction of material from all other RSC journals. Find more information about Crossref citation counts. Behzad Zeynizadeh, Masumeh Gilanizadeh. You’ve supercharged your research process with ACS and Mendeley! "Reproduced from" can be substituted with "Adapted from". This paper describes the use of cadmium sulfide quantum dots (CdS QDs) as visible-light photocatalysts for the reduction of nitrobenzene to aniline through six sequential photoinduced, proton-coupled electron transfers. Effect of CPC micelle on N-hetero-aromatic base promoted room temperature permanganate oxidation of 2-butanol in aqueous medium. Catalysis Communications 2019, 124, 71-75. Aniline is very important organic chemical in organic chemistry becuase it is used to produce more organic compounds. THIOL-ACTIVATED SODIUM BOROHYDRIDE REDUCTION OF NITRO COMPOUNDS. XX is the XXth reference in the list of references. In this manuscript, we reported that controllable chemoselective hydrogenation of nitrobenzene to produce aniline, azoxybenzene and azobenzene was realized over CQDs/ZnIn2S4 nanocomposite under visible light via simply regulating the reaction medium including the alkalinity and the hydrogen source. This paper describes the use of cadmium sulfide quantum dots (CdS QDs) as visible-light photocatalysts for the reduction of nitrobenzene to aniline through six sequential photoinduced, proton-coupled electron transfers. Bismuth-Mediated Solvent-Free One-Step Conversion of Nitroarenes to Azoxy- and Azoarenes. Herein we carried out the first work on the simultaneous transformation of If you are the author of this article you do not need to formally request permission Gold nanoparticles stabilized by phosphine-decorated polymer immobilized ionic liquids (AuNP@PPh2-PIILP) is an extremely efficient multiproduct selective catalyst for the sodium borohydride-mediated reduction of nitrobenzene giving N-phenylhydroxylamine, azoxybenzene, or aniline as the sole product under mild conditions and a very low catalyst loading. Benzene is heated with nitrating mixture to form nitrobenzene.The reaction is known as nitration .It is aromatic electrophilic substitution reaction. Reduction of nitrobenzene to aniline is oxidation reducing reaction.oxidation reducing reaction. If you are not the author of this article and you wish to reproduce material from An Overview of Synthetic Methods for Preparation of Nitrosoaromatic Compounds. http://pubs.acs.org/page/copyright/permissions.html, https://doi.org/10.1021/acs.orglett.9b01200, https://doi.org/10.1021/acssuschemeng.8b05291, https://doi.org/10.1021/acssuschemeng.7b02921, https://doi.org/10.1021/acs.chemrev.5b00482, https://doi.org/10.1016/j.apsusc.2020.147604, https://doi.org/10.1016/j.jmmm.2020.167225, https://doi.org/10.1016/j.cej.2020.125997, https://doi.org/10.1016/j.jallcom.2020.157947, https://doi.org/10.1007/s10562-020-03127-w, https://doi.org/10.1007/s11164-020-04126-7, https://doi.org/10.1007/s10562-019-02989-z, https://doi.org/10.1016/j.cattod.2018.10.035, https://doi.org/10.1007/s11696-019-00897-5, https://doi.org/10.7467/KSAE.2019.27.6.435, https://doi.org/10.1016/j.catcom.2019.02.026, https://doi.org/10.1016/j.ica.2019.02.010, https://doi.org/10.1016/j.jcat.2018.11.011, https://doi.org/10.1016/j.enmm.2018.04.005, https://doi.org/10.1038/s41467-017-02527-8, https://doi.org/10.1016/j.catcom.2018.07.019, https://doi.org/10.1016/j.tetlet.2018.08.053, https://doi.org/10.1016/j.apsusc.2018.02.099, https://doi.org/10.1016/j.jece.2017.10.028, https://doi.org/10.1016/j.jcis.2017.06.025, https://doi.org/10.1080/24701556.2017.1284093, https://doi.org/10.1016/j.catcom.2017.06.004, https://doi.org/10.1371/journal.pone.0158549, https://doi.org/10.1016/j.psep.2017.02.009, https://doi.org/10.1016/j.snb.2016.09.037, https://doi.org/10.1016/j.fuel.2016.02.051, https://doi.org/10.3184/174751916X14628044763653, https://doi.org/10.1007/s00339-016-9777-4, https://doi.org/10.1016/j.jcat.2016.01.007, https://doi.org/10.1016/j.matchemphys.2015.12.019, https://doi.org/10.1007/s10593-015-1656-y, https://doi.org/10.1016/j.apcatb.2014.05.012, https://doi.org/10.1016/j.catcom.2014.10.015, https://doi.org/10.1016/j.matchemphys.2014.09.029, https://doi.org/10.1016/j.apsusc.2014.07.158, https://doi.org/10.1016/j.molliq.2014.07.018. Go to our Authors contributing to RSC publications (journal articles, books or book chapters) 2 B. Zhou, J. or in a thesis or dissertation provided that the correct acknowledgement is given Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Umsetzung von Nitroaromaten mit Natriumborhydrid, III. Conversion (100%) and selectivity toward the desired azoxybenzene product were observed when the … You do not have JavaScript enabled. When the nitrobenzene:hydrazine molar ratio was adjusted to 1:0.5, the conversion was comparatively low (75%) with the azoxybenzene selectivity of 85% and aniline selectivity of 15%. If you are on a personal connection, like at home, you can run an anti-virus scan on your device to make sure it is not infected with malware. Efficient production of amino-, azo- and azoxy- aromatics is important in chemical industries. Please enable JavaScript Jih Ru Hwu,, Asish R. Das,, Chia Wei Yang,, Jiann-Jyh Huang, and, Ming-Hua Hsu. Please reconnect. https://doi.org/10.1016/j.jcat.2020.05.041. This article is cited by 14 publications. By continuing you agree to the use of cookies. contained in this article in third party publications Please enable JavaScript At pH 3.6–4.3, the internal quantum yield of photons-to-reducing electrons is 37.1% over 54 h of illumination, with no apparent decrease in catalyst activity. Instructions for using Copyright Clearance Center page for details. to reproduce figures, diagrams etc. the whole article in a third party publication with the exception of reproduction If you are not the author of this article and you wish to reproduce material from 1,2-Eliminations in a Novel Reductive Coupling of Nitroarenes to Give Azoxy Arenes by Sodium Bis(trimethylsilyl)amide. the Altmetric Attention Score and how the score is calculated. with the reproduced material. In the present study, we report an efficient and high yielding catalytic reduction of nitrobenzene in the presence of 2-propanol or molecular H2 over Fe doped BaTiO3 nanocatalysts.