Local exhaust ventilation usually required. If safe to do so, remove containers from path of fire. Acta, 1979, 33, 275-280. H228: Flammable solid DO NOT approach containers suspected to be hot. DOT: How old was queen elizabeth 2 when she became queen? Personal Protection: Consult your EHS staff for recommendations FOR PACKAGE STORAGE: Store in original containers in approved flame-proof area. Exporters to USA, Canada, UAE, Europe, South Africa, Tanzania, Kenya, Egypt, Turkey, Nigeria, Uganda, Brazil, Chile, Argentina, Dubai, Cameroon, Mexico, Brazil, Chile, Argentina, Korea, Thailand, Malaysia, Indonesia, Australia, China, Germany, France, etc. Several industrial accidents, which probably were due to such interactions, have occurred; this potential hazard often remains unacknowledged. What is the popular or general journal called in English? DSC studies of aromatic hydrocarbon picrates, Acute oral toxicity Category 3 IMDG Class: 4.1 IMDG Subrisk: None Acute dermal toxicity Category 3 ; Anvia, F.; Zhu, S.Z. Thermochim. Avoid contamination with oxidizing agents i.e. Disclaimer: ; Filatov, A.A., IUPAC names gives all the non-confidential names provided to ECHA in submissions under REACH, CLP, BPR and PIC, where indicated to be a IUPAC name. SRD 103a – Thermo Data Engine (TDE) for pure compounds. Explosives can supply own oxygen for combustion and smothering action of foam or dry chemical may be ineffective. Induce vomiting with fingers down the back of the throat, only if conscious. Note that this does not mean that they are properly structured names according to the IUPAC nomenclature. Try to avoid creating dust conditions. B: Background levels occur in specimens collected from subjects NOT exposed ; Desmarteau, D.D. Melting Range (°F): 251.6F Avoid reaction with oxidizing agents, bases and strong reducing agents. 14-sep-20. If skin or hair contact occurs, quickly but gently, wipe material off skin with a dry, clean cloth. Transport to hospital or doctor without delay. ... TRINITROPHENOL (PICRIC ACID… Use water delivered as a fine spray to control fire and cool adjacent area. Preferred IUPAC name. Like other highly nitrated organic compounds, picric acid … Alert Emergency Responders and tell them location and nature of hazard. Vapor Pressure (mmHG): < 0.26 @ 195C Aqueous biodegradation - Anaerobic - Low (hours): 48 ; Stillwell, R.N. C): Find compounds which contain this structure, Find compounds which resemble this structure, European Molecular POTENTIAL HEALTH EFFECTS AS PER LITERATURE: P361: Remove/Take off immediately all contaminated clothing. Odor: Not available. Skin and conjunctiva become yellow due to acidosis and jaundice. Aromatic nitro compounds range from slight to strong oxidizing agents. Biology Laboratory, InChI=1S/C6H3N3O7/c10-6-4(8(13)14)1-3(7(11)12)2-5(6)9(15)16/h1-2,10H, Oc1c(cc(cc1[N+]([O-])=O)[N+]([O-])=O)[N+]([O-])=O, TNP-ATP All rights reserved. Disposal by detonation: Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting the upper and lower lids. the Toxic by inhalation, in contact with skin and if swallowed. P312: Call a POISON CENTER or doctor/physician if you feel unwell. Transport to hospital, or doctor, without delay. R43 May cause sensitization by skin contact. Buffered solutions of picric acid produce lesions of significant severity in the range pH 1.5 to pH 9 with little significant difference. Keep container tightly closed. GHS, Globally Harmonized System Classification in accordance with 29 CFR 1910 jcamp-plot.js. Like other highly nitrated organic compounds, picric acid is an explosive, which was once its primary use. Koppel, I.A. Cool fire exposed containers with water spray from a protected location. Strange yellow vision is symptomatic of over-exposure, to picric acid, by this or other routes. Inhaled: Inhalation of vapors or aerosols (mists, fumes), generated by the material during normal handling, may produce toxic effects. ALS - Hussein Y. Afeefy, Joel F. Liebman, and Stephen E. Stein Representatives in Houston, Chicago and New York, USA shall not be liable for any damage that may result from Control personal contact by using protective equipment. oid shock, friction, heat. The relationship between energy of decomposition and processing hazards has been the subject of discussion; it is suggested that values of energy released per unit of mass, rather than on a molar basis (J/g) be used in the assessment. Assay: ------------------------ 98% ---------------------- 99,5% Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket mask as trained. 122 °C OU Chemical Safety Data (No longer updated) More details: 122 °C Jean-Claude Bradley Open Melting Point Dataset 15163: 122.5 °C Jean-Claude Bradley Open Melting Point Dataset 20993: 251-253 F (121.6667-122.7778 °C) Wikidata Q189298 252 F (122.2222 °C) Wikidata Q189298 122-123 °C (Literature) Sigma-Aldrich ALDRICH-197378 122.5 °C Kaye & Laby (No longer updated) It will also react with alkaline materials including plaster and concrete to form explosive materials. If risk of overexposure exists, wear an approved respirator. If handling picric acid contained in a jar, gently tilt bottle to see if crystals roll over each other - if they do the acid is dry and capable of explosion - contact personnel trained in the handling of explosives immediately P250: Do not subject to grinding/shock/friction. We can give all solid chemical materials as per specified size or shape.